Search results for "thermal [correlation function]"
showing 10 items of 1923 documents
Combined spectroscopic and theoretical analysis of the binding of a water-soluble perylene diimide to DNA/RNA polynucleotides and G-quadruplexes.
2021
We present here a combined spectroscopic and theoretical analysis of the binding of N,N’-bis(2-(1-piperazino)ethyl)-3,4,9,10-perylenetetracarboxylic acid diimide dichloride (PZPERY) to different biosubstrates. Absorbance titrations and circular dichroism experiments, melting studies and isothermal calorimetry (ITC) titrations reveal a picture where the binding to natural double-stranded DNA is very different from that to double and triple-stranded RNAs (poly(A)∙poly(U) and poly(U)∙poly(A)⁎poly(U)). As confirmed also by the structural and energetic details clarified by density functional theory (DFT) calculations, intercalation occurs for DNA, with a process driven by the combination of aggr…
Cytotoxic hydrophilic iminophosphorane coordination compounds of d8 metals. Studies of their interactions with DNA and HSA
2012
The synthesis and characterization of a new water-soluble N,N-chelating iminophosphorane ligand TPAN-C(O)-2-NC(5)H(4) (N,N-IM) (1) and its d(8) (Au(III), Pd(II) and Pt(II)) coordination complexes are reported. The structures of cationic [AuCl(2)(N,N-IM)]ClO(4) (2) and neutral [MCl(2)(N,N-IM)] M=Pd (3), Pt(4) complexes were determined by X-ray diffraction studies or by means of density-functional calculations. While the Pd and Pt compounds are stable in mixtures of DMSO/H(2)O over 4 days, the gold derivative (2) decomposes quickly to TPAO and previously reported neutral gold(III) compound [AuCl(2)(N,N-H)] 5 (containing the chelating N,N-fragment HN-C(O)-2-NC(5)H(4)). The cytotoxicities of co…
Reverse electrodialysis heat engine for sustainable power production
2017
Abstract Reverse Electrodialysis Heat Engine (REDHE) is a promising technology to convert waste heat at temperatures lower than 100 °C into electric power. In the present work an overview of the possible regeneration methods is presented and the technological challenges for the development of the RED Heat Engine (REDHE) are identified. The potential of this power production cycle was investigated through a simplified mathematical model. In the first part of the work, several salts were singularly modelled as possible solutes in aqueous solutions feeding the RED unit and the corresponding optimal conditions were recognized via an optimization study. In the second part, three different RED He…
Soil water content monitoring: a verification of thermal inertia approaches on low spatial, high temporal resolutions images
2013
Soil water content is directly connected with soil evaporation and plant transpiration processes; in particular, soil water content within the root zone, is readily available to evapotranspiration. Thus, in agricultural sciences, the assessment of the spatial distribution of soil water content could be of utmost importance in evaluating crop water requirement. In spite of limitations to applicability due to contingent cloud cover, water content of the upper part of the soil can be determined by applying the thermal inertia approach by coupling optical and thermal infrared images. The thermal inertia formulation, rigorously retrieved on bare soil, has been also verified on soils partially co…
Critical analysis of the thermal inertia approach to map soil water content under sparse vegetation and changeable sky conditions
2012
The paper reports a critical analysis of the thermal inertia approach to map surface soil water content on bare and sparsely vegetated soils by means of remotely sensed data. The study area is an experimental area located in Barrax (Spain). Field data were acquired within the Barrax 2011 research project. AHS airborne images including VIS/NIR and TIR bands were acquired both day and night time by the INTA (Instituto Nacional de Tecnica Aeroespacial) between the 11 th and 13 rd of June 2011. Images cover a corn pivot surrounded by bare soil, where a set of in situ data have been collected previously and simultaneously to overpasses. To validate remotely sensed estimations, a preliminary prox…
A Comprehensive Thermogravimetric Analysis Multifaceted Method for the Exact Determination of the Composition of Multifunctional Metal‐Organic Framew…
2020
Thermogravimetric analysis (TGA) has been widely used as a tool to characterise the composition of materials such as Metal-Organic Frameworks (MOFs). However, given their multifunctionality and structural complexity, examples of detailed methodologies for the exact calculation of the composition of complex MOF structures and MOF composites are lacking in the literature. Herein, we introduce a new straightforward methodology – based on the experimental ratio between the mass of a structure and its residue – for the exact calculation of the composition of almost any MOF material. We provide a detailed guide for the application of our methodology to different MOF materials, including MOFs in w…
Suitability of Illite Based Clays of Latvia for Chemical and Thermal Activation
2014
Materials has been synthesized in the temperature range from 600-800 0C from illite based clays of Latvia under activation of KOH and NaOH solutions (4-6 M). Compressive strength and apparent porosity were measured. The effect of the concentration of KOH and NaOH solutions on the material mechanical properties was investigated by means of infrared spectroscopy (IR). Compressive strength data of the materials showed that via such activation building materials with good quality can be obtained.
HTLS Conductors: A Way to Optimize RES Generation and to Improve the Competitiveness of the Electrical Market—A Case Study in Sicily
2018
Stringent environmental constraints make more difficult to identify new energy corridors and build new power lines. The increase in the generation of electricity from renewable energy sources (RESs) makes the operation of electrical systems increasingly difficult in some areas. The transmission system operators (TSOs), in Italy Terna, are forced to exploit the existing overhead transmission lines, increasing the possibility of dispatching energy, in particular RES, optimizing the transmission capacity. Therefore, after a brief presentation of the Sicilian electricity system and a brief description of high-temperature low-sag (HTLS) conductors, a case study is presented. It is shown how it i…
A review of thermochemical energy storage systems for power grid support
2020
Power systems in the future are expected to be characterized by an increasing penetration of renewable energy sources systems. To achieve the ambitious goals of the “clean energy transition”, energy storage is a key factor, needed in power system design and operation as well as power-to-heat, allowing more flexibility linking the power networks and the heating/cooling demands. Thermochemical systems coupled to power-to-heat are receiving an increasing attention due to their better performance in comparison with sensible and latent heat storage technologies, in particular, in terms of storage time dynamics and energy density. In this work, a comprehensive review of the state of art of theore…
Energy Conscious Building Design
1987
Since the beginning of energy crisis many design tools have been developed in order to enable the designer to cope with energy consumption in buildings. These tools are of different kind: from very sophisticated simulation models to simplified (often too much) methods. Each of them offers various advantages and disadvantages, and it is up to the designer to choose among them.